Molten Carbonate High Temperature Fuel Cells Getting to Scale

FuelCell Energy (FCE) is developing high-temperature fuel cells that can work with natural gas and coal plants to improve efficiency and cleaner energy. The Connecticut-based firm has developed a new type of fuel cell that uses molten carbonate electrolytes. This electrochemical cell can capture CO2 from a power plant’s flue gas while generating additional electricity…
Molten Carbonate High Temperature Fuel Cells Getting to Scale

FuelCell Energy (FCE) is developing high-temperature fuel cells that can work with natural gas and coal plants to improve efficiency and cleaner energy. The Connecticut-based firm has developed a new type of fuel cell that uses molten carbonate electrolytes. This electrochemical cell can capture CO2 from a power plant’s flue gas while generating additional electricity from natural gas, coal, or other fuels. The company has more than 100 US fuel-cell patents, big-name partners, and a soaring stock price. What it doesn’t have yet are profits or a marquee project that shows its technology pays off at commercial scale.

A fuel cell is a device that generates electricity through an electrochemical reaction, not combustion. There are some who claim that producing heat from hydrogen without combustion is unique or magical.

Real energy solutions have measured metrics to determine if they are economic to replace the entire coal burner or to add the fuel cell along side the coal plant. Molten carbonate fuel cells are clearly defined in terms of science, engineering, economics and scalability. There are pretenders that are not defined and are not performing transparent engineering design and cost studies and are not working towards clarifying actual potential benefits.

Molten-carbonate fuel cells (MCFCs) are high-temperature fuel cells that operate at temperatures of 600 °C and above.

Molten carbonate fuel cells (MCFCs) were developed for natural gas, biogas (produced as a result of anaerobic digestion or biomass gasification), and coal-based power plants for electrical utility, industrial, and military applications. MCFCs are high-temperature fuel cells that use an electrolyte composed of a molten carbonate salt mixture suspended in a porous, chemically inert ceramic matrix of beta-alumina solid electrolyte (BASE). Since they operate at extremely high temperatures of 650 °C (roughly 1,200 °F) and above, non-precious[dubious – discuss] metals can be used as catalysts at the anode and cathode, reducing costs.

Improved efficiency is another reason MCFCs offer significant cost reductions over phosphoric acid fuel cells (PAFCs). Molten carbonate fuel cells can reach efficiencies approaching 60%, considerably higher than the 37–42% efficiencies of a phosphoric acid fuel cell plant. When the waste heat is captured and used, overall fuel efficiencies can be as high as 85%

Design and tri-criteria optimization of an MCFC based energy system with hydrogen production and injection: An effort to minimize the carbon emission

The threat of rapid depletion of fossil fuel reserves and the discharge of pollutants due to the depletion of these resources has had catastrophic consequences for the ecosystem. Using efficient energy systems, waste heat recovery from these systems, and decreased carbon dioxide emission cycles is one approach to averting this looming threat in this context. It is proposed in this paper to utilize the electricity generated by the bottoming absorption power cycle to create hydrogen for use in a molten carbonate fuel cell-based energy system. The system is called near-zero carbon since the efficient waste heat utilization allows maximum hydrogen and minimum hydrocarbon fuel use. The concept of the near-zero carbon cycle is being explored from the viewpoints of technology, economics, and the environment. It is necessary to do multi-criteria optimization to establish the optimum operating point of the system under consideration to reduce costs and CO2 emissions while simultaneously increasing efficiency. A parametric analysis is performed to discover the important design parameters that impact the system’s performance under consideration. Included among the factors under investigation are the fuel utilization factor, current density, stack temperature (Tstack), and the steam to carbon ratio (rsc). Upon investigation, it was discovered that the suggested system had an energy and exergy efficiency of around 66.21% and 59.5%, respectively. According to the findings of the exergy analysis, the MCFC and afterburner ranked highest in terms of exergy destruction (93.12 MW and 22.4 MW, respectively). The tri-objective optimization findings also reveal that the most optimal solution point has an exergy efficiency of 59.5%, a total cost rate of 11.7 ($/gigajoule), and CO2 emission of 0.58 ton/MWh.

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